New Yorker Fiction Podcast
http://www.newyorker.com/online/podcasts/fiction
(available on iTunes)

This podcast is amazing. Authors read from stories posted in The New Yorker, then talk about various aspects of the story and the author. The stories are entertaining, of course, but hearing about the story framework, what was going on for the author when the story was written and other facts really bring the stories to life and help to provide a little more prospective about them.
This is a must for writers! The information is very helpful and can add a lot to an author’s toolbox.
A highly entertaining and interesting podcast.